Product ID:MIL L 46195A TYI (SA14947 GREEN)AEROSOL
MSDS Date:10/01/1989
FSC:8010
NIIN:01-016-1488
MSDS Number: BHNBM

KOPPERS COMPANY, INC.

436 SEVENTH AVENUE
PITTSBURGH, PA 15219
US

Emergency Phone: 800-553-5631/800-424-9300

Info Phone: 412-227-2911

Cage: EO463

KOPPERS COMPANY, INC.

PITTSBURGH, PA 15219-1818 US

Cage: EO463

N-BUTYL ACETATE (SARA III)

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 20-25%

OSHA PEL 150 PPM/200 STEL

ACGIH TLV: 150 PPM/200STEL;9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CARBON BLACK

CAS: 1333-86-4

RTECS: FF5800000

Fraction By Weight: 1-5%

OSHA PEL 3.5 MG/M3

ACGIH TLV: 3.5 MG/M3; 9192

IRON OXIDE

CAS: 1309-37-1

Fraction By Weight: 5-10%

OSHA PEL 10 MG/M3 (FE)

ACGIH TLV: 5 MG/M3(FE),B2; 9293

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 1-5%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

METHYL ETHYL KETONE (2-BUTANONE) (MEK) (SARA III)

CAS: 78-93-3

RTECS: EL6475000

Fraction By Weight: 15-20%

OSHA PEL 200 PPM/300 STEL

ACGIH TLV: 200 PPM/300STEL 9192

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 5-10%

OSHA PEL 200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

AMORPHOUS SILICON DIOXIDE

CAS: 61790-53-2

Fraction By Weight: 15-20%

OSHA PEL 20 MPPCF

ACGIH TLV: 10 MG/M3 TDUST; 9293

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:YES OSHA:YES
Health Hazards Acute and Chronic:INHALE:MAY CAUSE RESP TRACT IRR AND
CENTRAL NERVOUS SYS DEPRESSION.CHARACTER:
HEADACHE,WEAKNESS,DIZZINESS,INCOORDINATION,POSS
COLLAPSE.RPTD/PROLONGED INHALE OF AIRBORNE PARTICLES MAY LEAD TO
LUNG D ISEASE.FUMES MAY CAUSE METAL FUME
FEVER.CHARACTER:HEADACHE,DIZZINESS,METALLIC TASTE IN MOUTH,GEN
FLU-LIKE SYMPTOMS.
Explanation of Carcinogenicity:CRYSTALLINE SILICA, Z TOXIC HAVE BEEN
LISTED AS CARCINO- GENS.
Effects of Overexposure:SEE ABOVE. EYES: DIR CONTACT W/LIQ OR VAPOR MAY
CAUSE IRRITATION.
SKIN:DEFATTINGRED,CRACK,BLISTERING,IRR,DERMATITIS.MAY BE ABSBOR
THRU SKIN. INGEST:NAUSEA,VOMITDIARRHEA,SEE INHALE. ASPIRATION MAY
CAUS E CHEM PNEU CAN BE FATAL. FOR INHALE SEEABOVE.
Medical Cond Aggravated by Exposure:PRE-EXIST DISEASE/HISTORY OF
AILMENT INVOLVE SKIN,EYE,RESP TRACT,LIVER,KIDNEY,CENTRAL NERVOUS
SYS ARE AT A GREATER RISK THAN NORM OF DEVELOPE ADVERSE
EFFECTS WHEN EXPOSED TO THIS MATERIAL.

First Aid:EYE:IMMD FLUSH W/WTR FOR 15 MIN.SEEK MED AID. SKIN:WSH
W/SOAP&WTR.REDNESS,ITCH, BURN,OTHER SYPTMS,SEEK MED AID. WSH CONT
CLOTH. INHALE:REMVE FROM EXPOS. BREATH DIFF/STOPPED,CPR/OXYGEN.GET
MED AID. ING EST:DONT INDUCE VOMIT. 1 GLASS MILK/1-2OZ(30G-60G)
ACTIVATED CHARCOAL IN WTR AS TOLERATED. GET MED AID. DO NOT ATTEMPT
TO GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.

Flash Point Method:TCC
Flash Point:NR
Extinguishing Media:CARBON DIOXIDE,DRY CHEM/FOAM. WTR MAY BE
INEFFECTIVE. USE CARBON DIOXIDE,DRY CHEM,WTR SPRAY,ALCOHOL OR
UNIV FOAMS.
Fire Fighting Procedures:COMPLETE FIRE SERV PROT EQUIP,INCLUD FULL-FACE
MSHA/NIOSH APPRV BREAH APPARATUS.USE WATER TO COOL FIRE-EXPOSED
CONT/STRUCTURE/PROTECT PERSONNEL.
Unusual Fire/Explosion Hazard:VAPORS FORM FLAM/EXPLO MIX IN AIR.VAPORS
HEAVY,MAY TRAV GRND ETC TO IGN SOURCE. CONT MAY EXPLODE FROM EXT
HEAT. UNDER FIRE COND MAY EMIT IRR/TOXIC GAS/FUMES.

Spill Release Procedures:ELIM ALL SOURCES OF IGN.VENT AREA.AVOID
CONTACT W/HOT LIQ,FUMES HEAT SPARKS.USE INERT ABSORBENT. MUST
REPORT ENVIR RELEASE TO NAT RESPONSE CENTER. REPORTABLE QUANITY IS
100 LBS OR MORE. AVOID BREATHING VAPORS.STOP SPILL/LEAK IF NO
RISK INVOL.

Handling and Storage Precautions:AVOID PROLONGED OR REPEATED CONTACT
W/SKIN,EYES. AVOID PROLONGED BREATHING,MISTS OR FUMES. HANDLE AND
USE IN ACCORDANCE WITH OSHA REGULATIONS.
Other Precautions:NOTE TO PHYSICIAN:THERE IS NO SPEC ANTIDOTE FOR
EFFECT OF OVEREXPOSE.TREAT SYMP AND CLINICAL CONDITION. DONT USE
WITHOUT FULLY READING AND UNDERSTANDING MSDS. GROUND & BOND DRUMS.
DONT USE PRESSURE T O EMPTY DRUMS.

Respiratory Protection:IF VENT DOES NOT MAINTAIN INHALE EXP BELOW
PEL(TLV),USE MSHA/NIOSH APPRVED UNITSPER 29 CFR
1910.134,INSTRUC/WARN AND NIOSH-RESPIR DECISION LOGIC-PUB
#87.108.IF WITHIN OSH PROT FACTOR, AIR PURIFYING OV /FILTER UNITS
O.K.
Ventilation:SUFFICIENT GEN/LOC EXHAUST VENT IN PAT/VOL TO CONTROL EXPO-
SURE BELOW FLAM LIMITS.SEE OSHA REQ/NIOSH PUB 87-113.
Protective Gloves:INDUSTRIAL RESISTANT FLEXIBLE GLOVES.
Eye Protection:INDUST SAFETY GLASSES, MINIMAL.
Other Protective Equipment:SIDE SHIELDS,GOGGLES/FACESHIELD.CHEMICAL
GOGGLES IF SPLASH WEAR INDUSTRIAL CLOTHING, SAFETY FOOTWEAR.
Work Hygienic Practices:WASH EXPOSED AREAS PROMPTLY AFTER CONTACT. WASH
BEFORE EAT, DRINKING,USING TOBACCO PRODUCTS OR RESTROOMS.
Supplemental Safety and Health
DONT WEAR CONTACT LENS WITHOUT PROPER EYE PROTECTION WHEN USING
PRODUCT.EMPTY CONT MAY RETAIN PROD RESIDUE. DONT CUT,DRILL,GRIND
OR WELD NEAR FULL,PARTIALLY FULL OR EMPTY CONT. KEEP CONT CLOSED
STO RED IN COOL,DRY-VENTILATED AREA. PROTECTFROM PHYSICAL DAMAGE.
KEEP CONT CLOSED WHEN MATERIAL IS NOT IN USE.

Melt/Freeze Pt:M.P/F.P Text:NA
Vapor Density:> AIR
Spec Gravity:9.62 +/ -0.2*
pH:NA
Viscosity:82-92 KU
Solubility in Water:NEGLIGIBLE
Appearance and Odor:GREEN VISCOUS LIQUID WITH A TYPICAL SOLVENT ODOR.

Stability Indicator/Materials to Avoid:NO
AVOID OXIDIZING AGENTS, HEAT, SPARKS AND OPEN FLAME.
Stability Condition to Avoid:AVOID OXIDIZING AGENTS,HEAT,SPARKS AND
OPEN FLAME.
Hazardous Decomposition Products:CARBON MONOXIDE, CARBODN DIOXIDE UPON
THERMAL DECOMPOSITION.

Waste Disposal Methods:THIS PRODUCT IS A US EPA DEFINED IGNITABLE HAZ-
ARDOUS WASTE. DISPOSE OF AS AN IGNITABLE HAZAR- DOUS WASTE IN
ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.